Vladimir I. Bakhmutov (Bakhmoutov)
(born: June 7, 1948)
Texas A&M University, Department of Chemistry, TAMU P.O. Box 30012, College Station, Texas 77842-3012. Email: firstname.lastname@example.org. Ph: 979-845-8993
1971 M.S. in Chemistry, Moscow State University, Moscow, USSR.
1974 Ph.D. in Physical Inorganic Chemistry, Moscow State University, Moscow, USSR.
1984 Doctor of Science in Chemical Physics, Institute of Organo-Element Compounds, Academy of Sciences, Moscow, USSR.
of Professor of Chemistry
1991-1995 Head of NMR department Institute of Organo-Element Compounds,
Academy of Sciences, Moscow, USSR.
2002-present NMR spectroscopist at Department of Chemistry in the Texas A&M University
Professor, General Chemistry, Blinn College, College Station
2000-2002 Professor of Chemistry, Department of Chemistry, Centro de Investigacion
y de Estudios Avanzados del I. P. N. , A. P. 14-740, C. P. 07000, Mexico D. F. Mexico
1986-2000 Senior Researcher, Professor, Head of the NMR department, Institute of Organo-Element Compounds, Academy of Sciences of Russia, Moscow, Russia
1974- 1986 Researcher Fellow, NMR laboratory, Institute of Organo-element
compounds, Academy of Sciences of USSR, Moscow, USSR
PhD student, Department of Chemistry, Moscow State University, Moscow, USSR.
Research interests are at the interface of chemical physics and chemistry with wide applications of solution and solid-state NMR. They include currently weak proton-hydride bonding as organizing interaction in proton transfer and molecular aggregations and nuclear magnetic relaxation in porous silica-based materials particularly in paramagnetic solids.
Awards and Honors
Award for the best scientific work in organic chemistry, Academy of Sciences of the
Awards from Institute of Organo-element compounds, Academy of Sciences of the USSR
(1984, 1986, 1990, 1992)
Kabachnik Research Award, INEOS, Moscow, Russia (1997)
Medal from Russian Government for the best research work, Moscow, Russia (1997)
Medal and Award from the Cambridge International Centre, U.K. (1993)
Professorships form The Iberdrolla Group (Spain 1995)
Professorships form The Iberdrolla Group (Spain 1997)
the American Biographical Institute Award (1993)
1999 the Rennes University (France),
1995-1997 the University of Saragossa (Spain)
1994-1995 the University of Bourgogne (France)
1993 the University of Zurich (Switzerland).
Total number of PhD students: 20
Senior Advisor in Journal of Spectroscopy and Dynamics.
Reviewer in JACS, Inorganic Chemistry, Concepts in Nuclear Magnetic Resonance, Magnetic Resonance in Chemistry
Publications: more than 350 articles.
1. Bakhmutov VI. Strategies for Solid-State NMR Studies of Materials: From Diamagnetic to Paramagnetic Porous Solids, Chem. Rev., 2011, 111 (2), pp 530–562
2. Bakhmutov VI. NMR spectroscopy, “The Encyclopedia of Applied Spectroscopy’ , Wiley&Sons 2009.
3. Bakhmutov VI. ‘Proton Transfer to Hydride Ligands with Formation of Dihydrogen Complexes: Physicochemical View’. Eur. J. Inorg. Chem. 2005, 245.
4. Bakhmutov V.I. "NMR spin-lattice relaxation approaches to characterization of transition metal hydride complexes in solution". Rev. Inorg. Chem. 1998, 18, 183.
5. Bakhmutov V.I."NMR spectroscopy of polyfluorinated allyl cations", Russian Chem. Rev. 1988, 57, 839.
6. Bakhmutov V.I. "Dynamic NMR spectroscopy on rotation about C=C bonds in enamines containing the N-H bond", Bull. Magn. Reson. 1984, 6, 142.
Recent important publications:
1. Alisha M. Bohnsack, Ilich A. Ibarra, Vladimir I. Bakhmutov, Vincent M. Lynch, and Simon M. Humphrey Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Complexes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity J. Am. Chem. Soc., 2013, 135 (43), pp 16038–16041.
2. Brian M. Mosby, Agustín Díaz, Vladimir Bakhmutov, and Abraham Clearfield Surface Functionalization of Zirconium Phosphate Nanoplatelets for the Design of Polymer Fillers ACS Appl. Mater. Interfaces, 2014, 6 (1), pp 585–592.
3. Natalia V. Belkova, Ekaterina V. Bakhmutova-Albert, Evgenii I. Gutsul, Vladimir I. Bakhmutov, Igor E. Golub, Oleg A. Filippov, Lina M. Epstein, Maurizio Peruzzini, Andrea Rossin, Fabrizio Zanobini, and Elena S. Shubina Dihydrogen Bonding in Complex (PP3)RuH(η1-BH4) Featuring Two Proton-Accepting Hydride Sites: Experimental and Theoretical Studies Inorg. Chem., 2014, 53 (2), pp 1080–1090.
4. Tiffany L. Kinnibrugh, Ayi A. Ayi, Vladimir I. Bakhmutov, Jerzy Zoń, and Abraham Clearfield. Probing Structural Changes in a Phosphonate-based Metal–Organic Framework Exhibiting Reversible Dehydration Crystal Growth & Design, 2013, 13 (7), pp 2973–2981.
5. Vladimir I. Bakhmutov, Boris G. Shpeizer, Andrey V. Prosvirin, Kim R. Dunbar, Abraham Clearfield, On 29Si NMR relaxation as a structural criterion for studying paramagnetic supermicroporous silica-based materials: Silica-based materials incorporating Mn2+ ions into the silica matrix of SiO2–Al2O3–MnO. Solid State Nuclear Magnetic Resonance, Volume 36, Issue 3, November 2009, Pages 129-136.
6. Vladimir I. Bakhmutov The 29Si T1 and T2 NMR relaxation in porous paramagnetic material SiO2–MnO–Al2O3. Solid State Nuclear Magnetic Resonance, Volume 34, Issue 4, November 2008, Pages 197-201.
7. Vladimir I. Bakhmutov. On Hahn-echo measurements of short 29Si T2 times in some silica-based materials. Solid State Nuclear Magnetic Resonance, Volume 36, Issue 4, December 2009, Pages 164-166.
8. V. I. Bakhmutov, B. G. Shpeizer, A. Clearfield. Structure of a paramagnetic supermicroporous silica-based material via a multinuclear solid-state NMR monitoring Magn, Reson. Chem. 2006, 44, 985.
9. T.J. Taylor, V.I. Bakhmutov, F. P. Gabbai. Hydrocarbon Uptake in the alkylated micropores of a columnar supramolecular solid. Angew. Chem. 2006, 45, 1.
10. Bakhmutov, V.I.; Shpeizer, B.G., Clearfield, A. ‘29Si Spin-Lattice NMR Relaxation in Microporous Silica-Based Materials with high Mn+2 concentrations. Magn. Reson. Chem. 2006, 44, 985.